Quantitative Characterization of Organic Matters with Different Occurrences in Argillaceous Source Rocks: A Case of Shahejie Formation, Dongying Sag

新疆石油地质 ›› 2018, Vol. 39 ›› Issue (zk(English) ): 74-81.

Quantitative Characterization of Organic Matters with Different Occurrences in Argillaceous Source Rocks: A Case of Shahejie Formation, Dongying Sag

ZHAO Yue^1,2, CAI Jingong², LEI Tianzhu³, YANG Yan^{3, 4}

1. Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China;
2. State Key Laboratory of Marine Geology, Tongji University, Shanghai 200092, China;
3. Gansu Key Laboratory of Petroleum Resources/CAS Key Laboratory of Petroleum Resources, Lanzhou, Gansu 730000, China;
4. Jidong Oilfield Company, PetroChina, Tangshan, Hebei 063004, China

收稿日期:2017-11-29 修回日期:2018-03-05 出版日期:2019-01-01 发布日期:2021-05-19

Quantitative Characterization of Organic Matters with Different Occurrences in Argillaceous Source Rocks: A Case of Shahejie Formation, Dongying Sag

ZHAO Yue^1,2, CAI Jingong², LEI Tianzhu³, YANG Yan^{3, 4}

1. Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China;
2. State Key Laboratory of Marine Geology, Tongji University, Shanghai 200092, China;
3. Gansu Key Laboratory of Petroleum Resources/CAS Key Laboratory of Petroleum Resources, Lanzhou, Gansu 730000, China;
4. Jidong Oilfield Company, PetroChina, Tangshan, Hebei 063004, China

Received:2017-11-29 Revised:2018-03-05 Online:2019-01-01 Published:2021-05-19
About author:ZHAO Yue, E-mail: zhyue_1991@136.com

摘要/Abstract

摘要： The organic matters retained in argillaceous source rocks are of various occurrences, including free state and mineral-binding state organic matters which have quite different geochemical natures and different significance in detailed source rock evaluation. However, a comprehensive quantitative characterization technique for both occurrences has not been established yet. With the argillaceous source rocks sampled from the middle Es₃, the lower Es₃ and the upper Es₄ of the Shahejie Formation, Dongying sag, and based on the analysis on the changes of pyrolysis parameters during the processes of solvent extraction and sequential chemical treatment including the variations of free hydrocarbon, cracked hydrocarbon and TOC, the paper measures the abundance of the organic matters with different occurrences quantitatively and establishes a quantitative characterization method of retained organic matters with different occurrences. The results show that the quantity of soluble organic matters of mineral-binding state is quite large in the organic matters retained in source rocks. Traditional evaluation methods such as Rock-Eval pyrolysis method and chloroform bitumen A method have some limitations. Profound study on the geochemical characteristics of the organic matters of mineral-binding state will widen the knowledge of hydrocarbon generation theory and retained hydrocarbon occurrences.

关键词: Dongying sag, Shahejie Formation, argillaceous source rock, retained organic matter, occurrence, quantitative characterization, sequential chemical treatment, Rock-Eval pyrolysis

Abstract: The organic matters retained in argillaceous source rocks are of various occurrences, including free state and mineral-binding state organic matters which have quite different geochemical natures and different significance in detailed source rock evaluation. However, a comprehensive quantitative characterization technique for both occurrences has not been established yet. With the argillaceous source rocks sampled from the middle Es₃, the lower Es₃ and the upper Es₄ of the Shahejie Formation, Dongying sag, and based on the analysis on the changes of pyrolysis parameters during the processes of solvent extraction and sequential chemical treatment including the variations of free hydrocarbon, cracked hydrocarbon and TOC, the paper measures the abundance of the organic matters with different occurrences quantitatively and establishes a quantitative characterization method of retained organic matters with different occurrences. The results show that the quantity of soluble organic matters of mineral-binding state is quite large in the organic matters retained in source rocks. Traditional evaluation methods such as Rock-Eval pyrolysis method and chloroform bitumen A method have some limitations. Profound study on the geochemical characteristics of the organic matters of mineral-binding state will widen the knowledge of hydrocarbon generation theory and retained hydrocarbon occurrences.

Key words: Dongying sag, Shahejie Formation, argillaceous source rock, retained organic matter, occurrence, quantitative characterization, sequential chemical treatment, Rock-Eval pyrolysis

ZHAO Yue, CAI Jingong, LEI Tianzhu, YANG Yan. Quantitative Characterization of Organic Matters with Different Occurrences in Argillaceous Source Rocks: A Case of Shahejie Formation, Dongying Sag[J]. 新疆石油地质, 2018, 39(zk(English) ): 74-81.

参考文献

[1] CAI Jingong,SONG Mingshui,LU Longfei,et al. Organo-clay complexes in source rocks—a natural material for hydrocarbon generation[J]. Marine Geology ＆ Quaternary Geology,2013,33(3):123-131.
[2] DING Fei,CAI Jingong,SONG Mingshui,et al. The relationship between organic matter and specific surface area in <2 μm clay size fraction of muddy source rock[J]. Science China:Earth Sciences,2013,43(4):634-641.
[3] KENNEDY M J,PEVEAR D R,HILL R J.Mineral surface control of organic carbon in black shale[J]. Science,2002,295:657-660.
[4] GUAN Ping,XU Yongchang,LIU Wenhui.Preservation occurrence of organic matters in source rocks and its quantitative characterization[J]. Chinese Science Bulletin,1998,43(14):1 556-1 559.
[5] WANG Zhaoyun,CHENG Keming.The organic geochemical characteristics comparison and contributors of different existing state organic matter in carbonate rocks[J]. Acta Sedimentologica Sinica,2000,18(4):600-605.
[6] XIE Qilai,ZHOU Zhongyi,LU Mingyong.Organic matter enclosed in carbonate minerals: a kind of important hydrocarbon-producing matter[J]. Acta Mineralogica Sinica,2000,20(1):59-62.
[7] FARRIMOND P,LOVE G D,BISHOP A N,et al. Evidence for the rapid incorporation of hopanoids into kerogen[J]. Geochimicaet Cosmochimica Acta,2003,67:1 383-1 394.
[8] BISHOP A N,LOVE G D,MCAULAY A D,et al. Release of kerogen-bound hopanoids by hydropyrolysis[J]. Organic Geochemistry,1998,29:989-1 001.
[9] SUN Yongge,MEREDITH W,SNAPE C E,et al. Study on the application of hydropyrolysis technique to the description of organic matter in highly mature source rocks[J]. Oil & Gas Geology,2008,29(2):276-282.
[10] JIANG Qigui,LI Maowen,QIAN Menhui,et al. Quantitative characterization of shale oil in different occurrence states and its application[J]. Petroleum Geology & Experiment,2016,38(6):842-849.
[11] ZHENG Lunju,MA Zhongliang,HE Sheng.The new methods for quantitative evaluation secondary hydrocarbon generation potential of marine source rocks[J]. Acta Sedimentologica Sinica,2012,30(3):594-602.
[12] LU Shuangfang,ZHONG Ningning,XUE Haitao,et al. Kinetic research of secondary hydrocarbon generation of organic matters in carbonate source rocks and its significance[J]. Science in China Series D:Earth Sciences,2007,37(2):178-184.
[13] SONG Guoqi,ZHANG Linye,LU Shuangfang,et al. Resource evaluation method for shale oil and its application[J]. Earth Science Frontiers,2013,20(4):221-228.
[14] ZHANG Jinchuan,LIN Lamei,LI Yuxi,et al. Classification and evaluation of shale oil[J]. Earth Science Frontiers,2012,19(5):322-331.
[15] LIU Quanyou,LIU Wenhui,WANG Xiaofeng,et al. Comparisons of geochemical methods for assessment of hydrocarbon generating potential[J]. Petroleum Geology & Experiment,2007,29(1):88-94.
[16] ZENG Huasen,HUO Qiuli,ZHANG Xiaochang,et al. Source rock evaluation using the S₂-TOC plot from Rock-Eval pyrolysis[J]. Geochimica,2010,39(6):574-579.
[17] CHEN Z,LIU X,GUO Q,et al. Inversion of source rock hydrocarbon generation kinetics from Rock-Eval data[J]. Fuel,2017,194:91-101.
[18] LIAO L,WANG Y,CHEN C,et al. Kinetic study of marine and lacustrine shale grains using Rock-Eval pyrolysis:implications to hydrocarbon generation,retention and expulsion[J]. Marine and Petroleum Geology,2018,89:164-173.
[19] MAYER L M,SCHICK L L,HARDY K R,et al. Organic matter in small mesopores in sediments and soils[J]. Geochimica et Cosmochimica Acta,2004,68:3 863-3 872.
[20] ZHU X,CAI J,LIU W,,et al. Occurrence of stable. Occurrence of stable and mobile organic matter in the clay-sized fraction of shale :significance for petroleum geology and carbon cycle[J]. International Journal of Coal Geology,2016,160-161:1-10.
[21] LI Y,CAI J,WANG X,et al. Smectite-illitization difference of source rocks developed in saline and fresh water environments and its influence on hydrocarbon generation:a study from the Shahejie formation,Dongying depression,China[J]. Marine and Petroleum Geology,2017,80:349-357.
[22] XIA Yanqing,ZHANG Gengxin.Immature crude oils possibly mainly originating from primary soluble organic matter-I. direct evidences from saturated hydrocarbons[J]. Petroleum Geology & Experiment,2001,23(4):438-443.
[23] RAHMAN H M,KENNEDY M,LOHR S,et al. Clay-organic association as a control on hydrocarbon generation in shale[J]. Organic Geochemistry,2017,105:42-55.
[24] WU L M,ZHOU C H,KEELING J,et al. Towards an understanding of the role of clay minerals in crude oil formation,migration and accumulation[J]. Earth-Science Reviews,2012,115:373-386.
[25] SONG Yitao,LIAO Yongsheng,ZHANG Shouchun.Quantitative characterization of organic matters of two different occurrences in brackish-saline lacustrine source rocks and its significance[J]. Chinese Science Bulletin,2005,50(14):1 531-1 534.
[26] BU H,YUAN P,LIU H,et al. Effects of complexion between organic matter (OM) and clay mineral on OM pyrolysis[J]. Geochimica et Cosmochimica Acta,2017,212:1-15.
[27] CAI Yuwen,ZHANG Shuichang,HE Kun,et al. Effects of inorganic minerals in source rocks on hydrocarbon generation from organic matter[J]. Petroleum Geology & Experiment,2017,39(2):253-260.
[28] WANG Xingxin,CAI Jingong,BAO Yujin.Catalysis of clay mineral to organic matter in hydrocarbon genesis[J]. Marine Petroleum Geology,2006,11(3):27-38.
[29] YANG Yan,LEI Tianzhu,XING Lantian,et al. Oil generation abilities of chemically bound organic matter in different types of organic clay complexes[J]. Petroleum Geology & Experiment,2015,37(4):487-493.

Quantitative Characterization of Organic Matters with Different Occurrences in Argillaceous Source Rocks: A Case of Shahejie Formation, Dongying Sag

Quantitative Characterization of Organic Matters with Different Occurrences in Argillaceous Source Rocks: A Case of Shahejie Formation, Dongying Sag

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 3

编辑推荐

Metrics

本文评价

[1]	LIU Zhong, WANG Ning, ZHANG Yongping, LU Xiuqin, LI Zheng, GAO Yan. Division and Application of Gas/Water Occurrence Models in High⁃Rank Coal Reservoirs[J]. 新疆石油地质, 2021, 42(zk(English)): 109-115.
[2]	GAO Yang. Lower Limits of Physical Properties of Glutenite Reservoir in Lower Section of the 4^th Member of Shahejie Formation in Steep Slope Zone of Northern Dongying Sag[J]. 新疆石油地质, 2017, 38(zk(English) ): 36-44.
[3]	LYU Chuanbing, CHENG Tongran, ZHANG Feng, JI Youliang, LIANG Guanzhong, LI Yanguo. Depositional Characteristics and Hydrocarbon Exploration Significance of Shallow-Water Deltas: A Case Study of Upper Sha-1 Member in Chaheji Structural Belt of Baxian Sag, Bohai Bay Basin[J]. 新疆石油地质, 2016, 37(zk(English) ): 60-65.