›› 2019, Vol. 40 ›› Issue (6): 1-1.doi: 10.7657/XJPG20190617

• 论文 •    

页岩油可动性表征方法研究进展

朱晓萌1,朱文兵1,曹剑2,宋宇1,张冬梅1,胡守志1,李水福1   

  1. (1.中国地质大学(武汉) 资源学院,武汉 430074;1.南京大学 地球科学与工程学院,南京 210023)
  • 出版日期:2019-12-01 发布日期:2019-12-01

Research Progress on Shale Oil Mobility Characterization

ZHU Xiaomeng1, ZHU Wenbing1, CAO Jian2, SONG Yu1, ZHANG Dongmei1, HU Shouzhi1, LI Shuifu1   

  1. (1.School of Earth Resources, China University of Geosciences, Wuhan, Hubei 430074, China; 2.School of Earth Sciences and Engineering, Nanjing University, Nanjing, Jiangsu 210023, China)
  • Online:2019-12-01 Published:2019-12-01

摘要: 页岩油的可动性及其表征是页岩油研究的一项核心内容,但页岩油可动性表征难度很大,需要考虑的因素很多。为加深对页岩油可动性表征的理解,评述了页岩油可动性表征领域研究进展,提出了页岩油可动性表征未来可能的发展方向。页岩油主要以吸附态和游离态2种方式赋存,游离态是主要产能贡献者,游离油的表征及其可动性是核心,当前研究方法可分为直接表征法和间接计算法2大类。直接表征法可分为热解法和抽提法,实验和分析过程都比较繁琐。间接计算法也可分为2种,即基于页岩孔隙含油饱和度的计算法和基于页岩总含油量与页岩吸附油量的差减法,前者误差较大且计算值偏高,运用页岩总含油量与页岩吸附油量的差减法得到的是最大理论可动油量,其精度主要取决于页岩吸附油量的确定,而页岩吸附主要发生于有机质(干酪根),但干酪根对页岩油的吸附机理目前研究较少。因此,查明干酪根对石油液态烃的吸附能力及其产物组成的变化规律,进而揭示干酪根对页岩油的吸附机理,是当前页岩油可动性表征研究领域值得探索的新方向。

Abstract: The mobility of shale oil and its characterization are key issues of shale oil study. The paper reviews the research progress on shale oil mobility characterization and proposes the study directions for shale oil mobility characterization. Shale oil mainly has 2 kinds of occurrence, namely adsorbed state and free state. The former is the main contributor for petroleum productivity so that the free oil mobility and its characterization are very important. The research methods of free oil can be divided into 2 categories such as direct characterization and indirect calculation. Direct characterization is subdivided into pyrolysis method and extraction method, but the experiment and analysis processes of the both methods are very complicated. Indirect calculation method is subdivided into the calculation method based on oil saturation of shale and the difference subtraction method based on the difference between the total shale oil content and the adsorbed shale oil content, the former leads to large errors and higher calculation results and the latter can obtain the theoretical max. mobile oil content. The accuracy of the latter method depends on the determination of the adsorbed shale oil content. The adsorption to oil mainly occurs in the organic matter of shale, but the mechanism of adsorption of organic matter to shale oil still remains unclear. Therefore, the investigation and determination of the adsorption capacity of kerogen to liquid hydrocarbons and its product composition variations and further revealing the adsorption mechanism of kerogen to shale oil are the new directions of the study on shale oil mobility characterization

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