泥质烃源岩有机质保存研究

新疆石油地质 ›› 2011, Vol. 32 ›› Issue (6): 686-689.

泥质烃源岩有机质保存研究

樊馥^1,2, 蔡进功², 张永生¹, 崔海娜³

1.中国地质科学院矿产资源研究所,北京 100037;
2.同济大学海洋与地球科学学院海洋地质国家重点实验室,上海 200092;
3.中国石油吉林油田分公司勘探开发研究院,吉林松原 138000

收稿日期:2011-01-13 出版日期:2011-12-01 发布日期:2020-08-20
作者简介:樊馥（1982-）,女,内蒙古赤峰人,博士,油气地球化学,（Tel）15601382253（E-mail）fanfu2005612033@sina.com.
基金资助:
国家自然基金（40872089; 41072089）和国家重大油气专项（2008ZX05006-003）

A Review of Studies on Organic Matter Preservation in Muddy Source Rocks

FAN Fu^1,2, CAI Jin-gong², ZHANG Yong-sheng¹, CUI Hai-na³

1. Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China;
2. State Key Laboratory of Marine Geology, Tongji University, Shanghai 200092, China;
3. Research Institute of Exploration and Development, Jilin Oilfield Company, PetroChina, Songyuan, Jilin 138000, China

Received:2011-01-13 Online:2011-12-01 Published:2020-08-20

摘要/Abstract

摘要： 在泥质烃源岩中,存在多种有机质保存方式。除外部缺氧环境外,有机质通过降解缩聚、选择性保存、自然硫化以及黏土保护等得以稳定存在。不同保存机制的有机质,构成了干酪根中多样的有机质显微组分类型,并在生烃时间和生烃性能方面存在显著差异性,这可能是造成泥质烃源岩具有宽生烃区间的重要原因。对多种有机质保存机制进行深入认识,探讨不同保存机制与外部环境的关系,尤其是矿物与有机质的相互作用,可能是未来石油地质领域有机质保存研究中的重要问题。这对于深化油气成因理论研究,更科学地开展油气资源评价,探索油气勘探新领域,具有十分重要的意义。

关键词: 泥质烃源岩, 有机质保存, 降解缩聚, 自然硫化, 黏土保护, 选择性保存

Abstract: Many preservation ways of organic matter exist in the muddy source rocks. Besides the oxygen-deficient environment, the organic matter is stably preserved by the degradation and condensation, selectivity preservation, vulcanization and clay protection. The organic matters with different preservation mechanisms form the multiple organic micro-components, such as the sponge amorphism organic matter, configuration organic matter, sporomorph, and particle amorphism organic matter, etc. It is different evidently in the generating hydrocarbon time and the capacity of generating hydrocarbon, which is possible to lead to the wide interval of generating hydrocarbon in the muddy source rocks. In-depth understanding of the preservation mechanisms of organic matter, discussion of the relations of the different preservation mechanisms with each other and the relation between external sedimentary circumstance and organic matter preservation mechanisms, especially the interaction between minerals and organic matter, which are the essential and important problems to study on the organic matter in the future petroleum geology. It is of great significance for deepening the theory of oil and gas genesis, evaluating the oil and gas resources, exploring the new areas for petroleum exploration.

Key words: muddy source rock, organic matter preservation, degradation and condensation, natural vulcanization, clay protection, selectivity preservation

中图分类号:

TE112.1

樊馥, 蔡进功, 张永生, 崔海娜. 泥质烃源岩有机质保存研究[J]. 新疆石油地质, 2011, 32(6): 686-689.

FAN Fu, CAI Jin-gong, ZHANG Yong-sheng, CUI Hai-na. A Review of Studies on Organic Matter Preservation in Muddy Source Rocks[J]. Xinjiang Petroleum Geology, 2011, 32(6): 686-689.

参考文献

[1] 王铁冠,钟宁宁,侯读杰. 低熟油气形成机理与分布[M].北京:石油工业出版社,1995.
[2] Marc Pansu, Jacques Gautheyrou.Handbook of soil analysis———mineralogical , organic and inorganic methods[M]. Springer, 2006:289-322.
[3] 蔡进功,包于进,杨守业,等. 泥质沉积物和泥岩中有机质的赋存形式与富集机制[J]. 中国科学(D 辑),2007,37(2):234-243.
[4] 王行信,蔡进功,包于进. 黏土矿物对有机质生烃的催化作用[J]. 海相油气地质,2006,11(3):27-38.
[5] 王行信,周书欣. 有机黏土化学在油气生成研究中的意义[J]. 地质地球化学,1991,5(1):1-8.
[6] Brabara Ranson,Dongseon Kim,Miriam Kastner, et al.Organic matter preservation on continental slopes : importance of mineralogy and surface ares[J]. Ceochimica et Cosmochimica Acta. 1998,62(88):1 329-1 345.
[7] Laetitia Pichevin, Philippe Bertrand, Mohammed Boussafir.Organic matter accumulation and presesvation controls in a deep sea modern environment: an example from Namibian slope sediments[J]. Organic Geochemistry, 2004,35(5):543-559.
[8] Calvert S E, Pedersen T F.Geochemistry of recent oxic and anoxic marine sediments : implications for the geological record[J]. Marine Geology, 1993,113(1-2):67-88.
[9] Schulz H D, Dahmke A, Schinzel U, et al.Early diagenetic processes , fluxes and reaction rates in sediments of the South Atlantic[J]. Geochimica et Cosmochimica Acta, 1994,58(9):2 041-2 060.
[10] Nissenbaum A, Kaplan I R.Chemical and isotopic evidence for the in situ origin ofmarine humic substances[J]. Limnology and Oceanography, 1972,17(4):570-582.
[11] Van Krevlen D W. Coal: typology - chemistry -physics -Constitution, thirded[M]. Elsevier, The Netherlands, 1993.
[12] Derenne S, Largeau C, Berkaloff C, et al.Non-hydrolysable macromolecular constituents from outer walls of Chlorella fusca and Nanochlorum eucaryotum[J]. Phytochemistry, 1992,31(66):1 923-1 929.
[13] Largeau C, Derenne S, Casadevall E, et al.Pyrolysis of immature torbanite and of the resistant biopolymer (PRB A) isolated from extant alga Botryoccocus braunii: mechanism of formation and structure of torbanite[J]. Organic Geochemistry, 1986,10(4-6):1 023-1 032.
[14] Boom A, Sinninghe Damste J S, de Leeuw J W. Cutan, a common aliphatic biopolymer in cuticles of drought adapted plants[J]. Organic Geochemistry, 2005,36(4):595-601.
[15] Szklarz G, Leonowicz A.Cooperation between fungal laccase and glucose oxidase in the degradation of lignin derivatives[J]. Phytochemistry, 1986,25(11):2 537-2 539.
[16] MohammedBoussafir,ElisabethLallier-Verges.Accumulation of organic matter in the Kimmeridge clay formation(KCF):an update fossilization model for marine petroleum sourcerocks[J]. Marine and Petroleum Geology, 1997,14(1):75-83.
[17] Sinninghe-Damste J S, Ripjstra W I C, Kock-van Dalen A C, et al. Quenching of labile functionalized lipids by inorganic sulfur species: evidence for formation of sedimentary organic sulfur compounds at the early stage of diagenesis[J]. Geochimica et Cosmochimica Acta, 1989,53(6):1 343-1 355.
[18] 卢龙飞,蔡进功,包于进,等. 黏土矿物保存海洋沉积有机质研究进展及其碳循环意义[J]. 地球科学进展,2006,21(9):932-937.
[19] 王飞宇,傅家漠. 煤和烃源岩镜质体中超微细类脂体检出及意义[J]. 科学通报,1995,38(2):151-154.
[20] Mayer LM, Macko SA,CammenL. Provenance, concentration and nature of sedimentary organic nitrogen in the Gulf of Maine[J]. Marine Chemistry, 1988,25(3):291-304.
[21] Furukawa Y.Energy-filtering transmition electron microscopy(EFTEM) and electron energy loss spectroscopy(EELS) investigation of clay-organic matter aggregates in aquatic sediments[J].OrganicGeochemistry,2000,31(77):735-744.
[22] Weiss. Organic derivatives of clay minerals, zeolites and related minerals[C]. Organic Geochemistry, Methods and Results, New York, 1969: 739-775.
[23] Ruehrwein R A, Ward D W.Mechanism of clay aggregation by polyelectrolytes[J]. Soil Science, 1952,73(6):484-492.
[24] Mayer L M.Extent of coverage of mineral surfaces by organic matter in marine sediments[J]. Geochimica et Cosmochimica Acta, 1999,63(2):207-215.
[25] 关平,徐水昌,刘文汇. 烃源岩有机质的不同赋存状态及定量估算[J]. 科学通报,1998,43(14):1 556-1 559.
[26] Indraratne S P, Tee Boon Goh, Shindo H.Sorption of organic compounds by hydroxyl-interlayered clays through chelation and humification process[J]. 2007,139(3-4):314-320.
[27] Tissot B P,Welte D H .Petroleum formation and occurrence (2nd ed)[M]. Berlin: Springer-Verlag,1984:160-198.
[28] Snowdon L R, Powell T G.Immature oil and condensate modification by hydrocarbon generation modle for terrestrial organic matter[J]. AAPG Bulletin, 1982,66(6):775-778.
[29] Boussafir M, Gelin F, Lallier Verges E, et al.Electron microscopy and pyrolysis of kerogens from the Kimmeridge clay formation,UK: source organisms, preservation processes, and origin of microcycles[J]. Geochimica et Cosmochimica Acta. 1995,59(18):3 731-3 747.
[30] 萧德铭,黄福堂,迟元林,等. 松辽及外围盆地未熟-低熟油地球化学[M]. 北京:石油工业出版社,2000,15-84.
[31] 李贤庆,包建平,熊波. 苏北盆地低熟烃源岩生烃组分剖析[J]. 江汉石油学院学报,1999,21(1):22-28.
[32] 张永刚,蔡进功,许卫平,等. 泥质烃源岩中有机质富集机制[M]. 北京:石油工业出版社,2007.
[33] LU Xiancai, LIU Qing, ZHANG Lingye, et al.Desorption sequence of organic matter from organoclay complexes in source rocks[C]. Goldschmidt Conference Abstracts, 2006.