Pyrrolic Compounds and Application in Hydrocarbon Migration

Abstract

Abstract: The basic geochemical property, the separation and ana lysis techniques, distribution pattern and geochemical significance (i.e.,maturity, sedimentary environment and original source material, etc.) of pyrrolic compounds in petroliferous geologic bodies and the effect on hydrocarbon migration are presented. The recent research state and the applying cases at home and abroad are reviewed. It is pointed out that the research and application of pyrrolic compounds to petroleum migration greatly promote the development of non-hydrocarbon geochemistry. Also, some limitations of the compounds application to the petroleum migration are given, such as that the crude sample should be obtained from the same kitchen; and how the maturity influences on its distribution is unknown yet.

Key words: pyrrolic compounds, separation, distribution, hydrocarbon migration

CLC Number:

NI Chun-hua, BAO Jian-ping, ZHANG Bao, SONG Huan-xin. Pyrrolic Compounds and Application in Hydrocarbon Migration[J]. Xinjiang Petroleum Geology, 2005, 26(4): 428-431.

References

[1] Yamamoto M.Fraction of azaarenes during oil migation[J].Organic Geochemistry,1992,19(4-6):389-402.
[2] Li M,LarterS R,Stoddart D,et al.Practical liquid chromatographic separation schemes for pyrrolic and pyridinic nitrogen aromatic heterocycle fraction from crude oils suitable for rapid characterization of geochemical samples[J].Analytical Chemistry,1991,64:1 337-1 344.
[3] Chen M.Response of pyrrolic and phenolic compounds to petroleum migration and in reservoir process,[D].Ph.d.Thesis.University of Newcastle upon Tyne,U.K.,1995.32-140.
[4] Li Maowen,Larter S R,Stoddart D,et al.Fractionation of pyrrolic nitrogen compound in petroleum during migration: derivation of mi gration-related geochemical parameters [A].Cubitt J M,England W A.The Geochemistry of Reservoirs[C].Geological Society of london,Special Pubication,1995.103-123.
[5] 刘洛夫,徐新德,毛东风,等咔唑类化合物在油气运移研究中的应用初探[D].科学通报,1997,42(4):420-423.
[6] 刘洛夫,康永尚.运用原油吡咯类含氮化合物研究塔里木盆地塔中地区石油的二次运移[J].地球化学,1998,27(5):475-482.
[7] 刘洛夫,毛东风石油运移研究的新方法DJ].地球科学进展,1996,11(6):607-610.
[8] 刘洛夫.塔里木盆地群4井原油吡咯类含氮化合物地球化学研究[J].沉积学报,1997,15(2):184-187.
[9] 李素梅,王铁冠,张爱云.地质体中的有机氮化合物及其在油藏地球化学中的应用[J].地质地球化学,1999,27(1): 100-107.
[10] 熊英,程克明.中性含氮化合物在酒西盆地石油运移研究中的应用[D].石油勘探与开发,1999,26(5):27-31.
[11] 侯建国.利用含氮化合物研究苏北盆地油气运移[D].江汉石油学院学报,2001 ,23:31-33.
[12] 李素梅,王铁冠,张爱云,等.原油中吡咯类化合物的地球化学特征及其地球化学意义[J].沉积学报,1999,17(2):312-317.
[13] Dorbon M,Ignatiadis I,Schitter J M,et al.Identification of carbazoles and benzocarba-zoles in a coker gas oil and influence of catalytic hydrotreatment on their distribution [J].Fuel,1984,63:565-570.
[14] Larter Douglas W,Lee Milton L,Bartle Keith D,et al.Chemical class separation and Characterization of organic compounds in synthetic fuels[D].Analytical Chemistry,1981,53:1 612-1 620.
[15] 包建平,马安来.原油中烷基苯酚和中性含氮化合物的快速分离与分析[J].江汉石油学院学报,1998,20(2):1-5.
[16] 李素梅,张爱云,王铁冠.原油中吡咯类含氮化合物的分布型式[J].石油与天然气地质,2000,21(2):118-122.
[17] 李素梅,刘洛夫,王铁冠.生物标志化合物和含氮化合物作为油气运移指标有效性的对比研究[J].石油勘探与开发,2000,27(4):95-98.
[18] 张敏,梅博文,向廷生.原油中的咔唑类化合物[D].科学通报,1997 ,42(23):2411-2414.
[19] 朱扬明,傅家谟,盛国英,等.塔里木盆地不同成因原油吡咯氮化合物的地球化学意义[J].科学通报,1997,42(23):2528-2531.