›› 2014, Vol. 35 ›› Issue (2): 1-1.

• 论文 •    

页岩气赋存力学机制

左罗1,2,3,熊伟1,2,郭为1,2,3,高树生1,2,胡志明1,2   

  1. (1.中国科学院渗流流体力学研究所,河北廊坊065007;2.中国石油勘探开发研究院廊坊分院,河北廊坊065007;3.中国科学院大学物理学院,北京100190)
  • 出版日期:2019-01-01 发布日期:1905-07-11

The Mechanism of Occurrence State of Shale Gas

ZUO Luo1,2,3, XIONG Wei1,2, GUO Wei1,2,3, GAO Shusheng1,2, HU Zhiming1,2   

  1. (1.Institue of Porous Flow and Fluid Mechanics, Chinese Academy of Sciences, Langfang, Hebei 065007, China; 2.Langfang Branch, Research Institute of Petroleum Exploration and Development, Langfang, Hebei 065007, China; 3.School of Physics, University of Chinese Academy of Sciences, Beijing 100190, China)
  • Online:2019-01-01 Published:1905-07-11

摘要: 从页岩孔隙类型及大小出发,详细分析了页岩气在各类孔隙中的受力情况,并借助Lee势能函数分析了页岩气在各类孔隙中的赋存状态。指出,页岩孔隙大体上可分为有机质孔隙、黏土矿物孔隙和非黏土矿物孔隙3大类,甲烷分子在各类孔隙中主要受到色散力作用,靠近孔隙壁面的气体分子受到孔隙壁面分子色散力作用被吸附,未受到壁面作用的分子则在孔隙中央呈游离状态;随着页岩各类孔隙孔径的增大,孔隙中受壁面分子影响的区域比例变小,孔隙的吸附能力减弱,吸附气主要赋存在小于10 nm的孔隙中;含有大量微孔隙的有机质和黏土的吸附能力比其他矿物强;在有机孔和黏土孔中页岩气以吸附气和游离气的方式存在,而在矿物孔中主要以游离气方式存在。

Abstract: The forces and the occurrence states of shale gas in various pore types are analyzed by different types and sizes of pores and by means of Lee potential?energy function. It is suggested that shale pores can mainly be divided into three types: organic pore, clay mineral pore and nonclay mineral pore, and each pore has its typical feature; the methane molecules in each pore are effected by dispersion force, some methane molecules near the pore walls are adsorbed by dispersion force, some are in free state when they are not effected by the force; with the increase of shale pore sizes, the proportion of area affected by pore wall is decreased and the adsorption ability of pores goes down; the adsorbed gas is mainly distributed in the pores less than 10 nm, the adsorption abilities of the organic matter and the clays with lots of micropores are higher than other minerals; in organic and clay pores, the shale gas exists by way of adsorbed gas and free gas, while in mineral pore, it does by free gas

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