GC-MS-MS 方法检测时代相关生物标志物及地质意义

新疆石油地质 ›› 2007, Vol. 28 ›› Issue (3): 315-319.

GC-MS-MS 方法检测时代相关生物标志物及地质意义

韩霞^1,2, 田世澄¹, 张占文², 王培荣³, 吴拓²

1.中国地质大学, 北京 100083;
2.中国石油辽河油田分公司勘探开发研究院, 辽宁盘锦 124010

收稿日期:2006-09-05 修回日期:2006-10-26 出版日期:2007-06-01 发布日期:2020-07-31
作者简介:韩霞(1964-), 女, 河北孟村人, 高级工程师, 在读博士研究生, 石油地质,(Tel) 0427-7807355-5(E-mail) Hanxia99@126.com.

The Age-Related Biomarkers Tested by GC-MS-MS Technologies and Their Geological Significances

HAN Xia^1,2, TIAN Shi-cheng¹, ZHANG Zhan-wen², WANG Pei-rong³, WU Tuo²

1. China University of Geosciences, Beijing 100083, China;
2. Research Institute of Exploration and Development, Liaohe Oilfield Company, PetroChina, Panjin, Liaoning 124010, China;
3. Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China

Received:2006-09-05 Revised:2006-10-26 Online:2007-06-01 Published:2020-07-31

摘要/Abstract

摘要： 利用色谱-质谱-质谱(GC-MS-MS)方法在辽河与塔里木盆地源岩和原油样品中,检测出了多个系列时代相关及特定种属生物标志物,包括:降胆甾烷系列、甲基甾烷及甲藻甾烷系列、三环二萜烷及四环二萜烷系列、六环藿烷及甲基藿烷系列等等,这些化合物很难用常规GC-MS方法检测到。以往认识的许多中生代以后才出现的生物标志物却在塔里木盆地寒武系源岩中有高含量分布,其先驱物的繁盛时代有可能推至更古老的寒武纪生物大爆发时代,GC-MS-MS方法检测出的特定种属和时代意义生物标志物参数提供了分子证据,并很好地区分了塔里木盆地寒武系与中-上奥陶统原油,在争议已久的塔里木油源问题研究中发挥了重要作用。

关键词: 塔里木盆地, 色谱, 质谱, 检测, 生物标志物

Abstract: By means of GC-MS-MS method, the multiple series of age-related and taxon specific biomarkers are tested in source rocks and oil samples from Liaohe oilfield and Tarim basin, which are hard to be detected by conventional GC-MS method. They are steranes, methylsteranes, Tricyclic and tetracyclic diterpanes, methyl hopanoid alkanes and hexacyclic hopanoid alkanes, etc. High content of norsteranes and Dinosteranes that were found after Mesozoic broadly occurred in Cambrian source rocks in Tarim basin, postulating that the precursors might even exist in the period of Cambrian biologic explosions. These molecular evidences and age-related significance given by GC-MS-MS method have been used for distinguishing the crude oils of Middle-Upper Ordovician from Cambrian in Tarim basin, playing an important role in approach to Tarim oil sources that have disputed for a long time.

Key words: Tarim basin, gas chromatography (GC), mass spectrography (MS), detection, biomarker

中图分类号:

TE112.11

韩霞, 田世澄, 张占文, 王培荣, 吴拓. GC-MS-MS 方法检测时代相关生物标志物及地质意义[J]. 新疆石油地质, 2007, 28(3): 315-319.

HAN Xia, TIAN Shi-cheng, ZHANG Zhan-wen, WANG Pei-rong, WU Tuo. The Age-Related Biomarkers Tested by GC-MS-MS Technologies and Their Geological Significances[J]. Xinjiang Petroleum Geology, 2007, 28(3): 315-319.

参考文献

[1] Moldowan J M. Trails of life[J]. Chemistry in Britain, 2000,36: 34-37.
[2] Peters K E, Moldowan J M. The biomarker guide: interpretingmolecular fossils in petroleumand ancient sediments[M].Printice-Hall, Englewood Cliffs, NJ, 1993.
[3] Moldowan J M, Chen Z, Wei Z, et al. High resolution geochemical technologies(HRGTs) applied to understanding petroleum systems in Saudi Arabia[A] //AAPG-2004 6th international con-ference on petroleum geocyemistre and exploration in the Afro Asian region[C]. 2004: 108-109.
[4] Moldowan J M, Huizinga B J, Dahl J, et al. The molecular fossil record of oleanane and its relationship to angiosperms[J]. Science, 1994, 265: 768-771.
[5] Holba A G, Dzoul I P, Masterson W D, et al. Application of 24-norcholestanes for constraining source age of petroleum[J]. Organic Geochemistry, 1998, 29: 1 269-12 83.
[6] Holba A G, Tegelaar E, Huizinga B J, et al. 24-norcholestanesas age-sensitive molecular fossils[J]. Geology, 1998B,26: 783-786.
[7] Moldowan J M, Dahl J, Jacobson S R, et al, Chemostratigraphic reconstruction of biofacies: molecular evidence linking cyst-forming dinoflagellates with pre-Triassic ancestors[J].Geology, 1996, 24: 159-162.
[8] Moldowan J M, Talyzina N M. Biogeochemical evidence for dinoflagellate ancestors in the Early Cambrian[J]. Science,1998, 281: 168-170.
[9] 孟凡巍, 周传明, 尹磊明, 等. 最古老的沟鞭藻: 来自山西永济中元古代晚期的化石和分子生物学证据[J]. 科学通报, 2005, 50(12): 1234-1238.
[10] McCaffrey MA,Moldowan J M, Lipton P A, et al. Paleoenvironmental implications of novel C30 steranes in Precambrian to Cenozoic age petroleum and bitumen[J]. Geochimica et Cosmochimica Acta, 1994, 58, 529-532.
[11] Moldowan J M, Seifert W K, Gallegos E J. Relationship between petroleum composition and depositional environment of petroleum source rocks[J]. AAPG Bulletin, 1985, 69:1 255-1 268.
[12] Goodman D K. Dinoflagellate cysts in a ancient and mordem sediments[A] // Taylor J F Red. The biology of dinoflag ellates[C]. Bot Monog, 1987, 21: 649-722.
[13] Helby R, Morgan R, Partridge A D. A palynological zonation of the Australian Mesozoic, in Studies in Australian Mesozoic Palynology(ed. Jell P A) [J]. Association of Australian Palaeontologists, Sydney, 1987: 1-94.
[14] Lipps J H. Fossil prokaryotes and protist[M]. Boston,Massachusetts:Blackwell scientific Publication, 1993: 155-167.
[15] 韩霞, 吴拓, 王培荣, 等. 生物标志物色谱质谱-质谱分析技术及地质应用[A] //第四届全国石油地质实验技术及实验室管理工作交流会议论文集[C]. 北京: 石油工业出版社1993: 96-100.
[16] 张水昌, 梁狄刚, 黎茂稳, 等. 分子化石与塔里木盆地油源对比[J]. 科学通报, 2002, 47(增刊): 16-30.